蔡正国
发布人: 星禧   发布时间: 2018-05-21    浏览次数:

蔡正国

博士

教授

高分子科学与工程系

博士生导师

caizg@dhu.edu.cn



·研究方向:

配位聚合与大分子设计;新型成纤高聚物设计、合成及应用研究


·荣誉获奖:

   12012年度教育部新世纪优秀人才支持计划

   22012年度曙光计划项目

   32010年度日本高分子研究奖励赏

   42006年度国家优秀自费留学生奖学金


·学习及工作经历:

 1993.9 - 1997.7: 吉林工学院,高分子材料,学士

 2002.9 - 2004.7: 日本东京工业大学,高分子化学与物理,硕士(导师:Takeshi   SHIONO

 2004.9 - 2007.3: 日本广岛大学,高分子化学与物理,博士(导师:Takeshi   SHIONO

 2010.8 - 2011.1: 美国芝加哥大学,访问学者

 2007.4 - 2011: 日本广岛大学,助理教授

 2011- 澳门·永利集团3044,教授


·主讲课程:

高分子化学、高分子合成化学


·主要论文:

  

1. Song, X.; Cao, L.; Tanaka, L.; Shiono, T.*; Cai, Z.* Optically Transparent Functional Polyolefin Elastomer with Excellent Mechanical and Thermal Properties ACS Macro Lett. 2019, 8, 299-303.

2. Structurally Simple Dinuclear Nickel Catalyzed Olefin Copolymerization with Polar Monomers, Cheng, H.;Wang, H.; Li, Y.; Hu, Y.; Zhang, X.*; Cai, Z.* J. Catal.2018, 368, 291-297.

3. Efficient Ethylene Copolymerization with Polar Monomers Using Palladium Anilinonaphthoquinone Catalysts. Ding, L.; Cheng, H.; Li, Y.; Tanaka, R.; Shiono, T.*; Cai, Z.* Polym. Chem.2018, 9, 5476-5482.

4. Wang, H.;Cheng, H.; Tanaka, R.; Shiono, T.*; Cai, Z.* Efficient Control of Ethylene–Norbornene Copolymerization Behavior of a Fluorenylamidoligated Titanium Complex: Substituent Effects of The Amido Ligand and Copolymer Properties, Polym. Chem.2018, 9, 4492-4497.

5. Wang, H.; Li, Y.; Cai, Z.* Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C1-Symmetric ansa-Silylene(Fluorenyl)(Amido) Dimethyl Titanium Complexes, Polymers2018, 9, 1075-1084.

6. Cheng, H.; Cai, Z.* (Anilino)anthraquinone Nickel-Catalyzed Random Copolymerization of Norbornene and Ethylene, ChemCatChem2018, 10, 497-500.

7Neutral Nickel(II) Complexes Bearing Aryloxide Imidazolin-2-imine Ligands for Efficient Copolymerization of Norbornene and Polar Monomers, Li, M.; Cai, Z.*; Eisen, M.S.* Organometallics2018, 37, 4753-4762.

8. Li, M.; Shu, X.; Cai, Z.*; Eisen, M.S.* Synthesis, Structures and Norbornene Polymerization Behavior of Neutral Nickel(II) and Palladium(II) Complexes Bearing Aryloxide Imidazolidin-2-imine Ligands, Organometallics2018, 37, 1172-1180.

9. Cheng, H.; Su, Y.; Hu, Y.; Zhang, X.; Cai, Z.* Ethylene Polymerization and Copolymerization with Polar Monomers Using Nickel Complexes Bearing Anilinobenzoic Acid Methyl Ester Ligand, Polymers2018, 10, 754-763.

10. Song, X.; Ma, Q.; Cai, Z.*Synthesis of Hydroxy-functionalized Ultrahigh Molecular Weight Polyethylene Using Fluorenylamidotitanium Complex, Chines J. Polym. Sci. 2018, 36, 171-175.

11. Fu, X.; Zhang, L.; Tanaka, R.; Shiono, T.*; Cai, Z.* Highly Robust Nickel Catalysts Containing Anilinonaphthoquinone Ligand for Copolymerization of Ethylene and Polar Monomers, Macromolecules2017, 50, 9216-9221.

12. Song, X.; Yu, L.; Shiono, T.*; Cai, Z.* Synthesis of Hydroxy-Functionalized Cyclic Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin , Macromol. Rapid Commun.2017, 38, 1600815.

13. Sun, Y.; Xu, B.; Shiono, T.*; Cai, Z.* Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts with Low Load of Methylaluminoxane for Syndiotactic-Specific Living Polymerization of Propylene, Organometallics2017, 36, 3009-3012.

14. Sun, Y.; Li, S.; Shiono, T.*; Cai, Z.* Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex, Polymers2017, 9, 632-641.

15. Song, X.; Ma, Q.; Cai, Z.*; Tanaka, R.; Shiono, T.*; Grubbs, R.B.* Facile Synthesis of Novel Polyethylene-Based A-B-C Block Copolymers Containing Poly(methyl methacrylate) using a Living Polymerization System, Macromol. Rapid Commun.2016, 37, 227-231.

授权专利:

  1. 苯胺蒽醌后过渡金属配合物及其制备方法与应用,蔡正国、程程龙,ZL 201610693376.4

  2. 苯氧2-亚胺咪唑烷金属配合物及其制备方法和应用,蔡正国、李明远,ZL 201610693597.1

  3. 超高分子量乙烯/苯乙烯类共聚物及其制备方法,蔡正国、马琼、袁浩波,ZL 201610693547.3

  4. 功能性超高分子量聚乙烯及其制备方法,蔡正国、马琼、李天佑、史新豪、郭敏,ZL 201610693533.1

  5. 一种功能性环烯烃/苯乙烯类共聚物及其制备方法,蔡正国、周健,ZL 201610693531.2

  

  

近几年承担的科研项目:

国家自然科学基金面上项目三项(21174026, 21474013, 21774018),主持人

澳门·永利集团3044中央高校基本科研业务费专项资金(励志计划项目),主持人

澳门·永利集团3044基本科研业务费(追加)专项资金,主持人

日本国家科学研究费,环烯烃共聚物的精密合成,项目负责人;

日本学术振兴会青年学者海外派遣基金,乙烯与极性单体的共聚合,主持人